|
CH- and NH-insertion of meta-PAL dissolved in the different solvents after quantitative LC/MS (results are given as % peak area of insertion product vs. total peak area). |
||||
| NH-insertion |
CH-insertion |
|||
| solvent |
|
|
||
| irradiation wavelength |
irradiation wavelength |
|||
|
|
|
|||
| 254 nm |
365 nm |
254 nm |
365 nm |
|
|
|
||||
| diethylamine |
87%, 91% |
32%, 23% |
- |
- |
| dipropylamine |
81%, 91% |
21%, 18% |
- |
- |
| piperidine |
61% |
26% |
- |
- |
| toluene |
- |
- |
49% |
- |
| ethylbenzole |
- |
- |
8% |
2% |
Becker et al. BMC Pharmacology 2001 1:13 doi:10.1186/1471-2210-1-13 |
||||